Yeah, this post is old, but Tory/Toui from the Deoxys Pokemon movie initially seems to hate/fear Pokemon, but he actually cares for them, he just can't stand touching them because he was caught in the middle of a stampede as a little kid.

... yeah, slightly dark backstory, but he's not angsty. He's sweet, very shy, but cheerful and kind. He bakes cookies and stuff! ;3;